Method for producing chiral smectic liquid crystal device including masking areas between electrodes, rubbing, removing mask, and rubbing again

ABSTRACT

A liquid crystal device comprising a first substrate on which a first group of belt-shaped electrodes are formed, a second substrate on which a second group of belt-shaped electrodes are formed so as to cross the first group of belt-shaped electrodes, and a chiral smectic liquid crystal arranged between the first and second substrates. A first pretilt angle of the liquid crystal on the first group of belt-shaped electrodes differs from a second pretilt angle of the liquid crystal in the spaces among the belt-shaped electrodes. The difference in pretilt angles is created by forming a resist over the spaces between the belt-shaped electrodes, rubbing, removing the resist, and rubbing again.

This application is a division of application Ser. No. 07/834,391 filed Feb. 12, 1992, now U.S. Pat. No. 5,223,963.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The invention relates to a device using a chiral smectic liquid crystal which exhibits ferroelectricity and also relates to a display apparatus.

2. Related Background Art

With respect to a display apparatus using a ferroelectric chiral smectic liquid crystal, there have been known display apparatuses in each of which a ferroelectric chiral smectic liquid crystal (hereinafter, referred to as an FLC) is injected in a liquid crystal cell which is constructed by arranging two glass substrates in which transparent electrodes are formed on inner surfaces and an orienting process has been performed so as to face each other while keeping a cell gap of about 1 to 3 μm as disclosed in, for instance, U.S. Pat. Nos. 4639089, 4681404, 4682858, 4712873, 4712874, 4712875, 4712877, 4714323, 4728176, 4738515, 4740060, 4765720, 4778259, 4796979, 4796980, 4859036, 4932757, 4932758, 5000545, and 5007716, and the like.

Among the above background arts, in particular, a device in which the FLC is oriented by forming a chevron structure shown in FIG. 1 has excellent light state under a cross nicols, so that a large enough contrast is obtained. FIG. 1 shows a cross sectional view of an orienting state of the FLC arranged between substrates 11 and 12. An FLC 13 forms a layer 15 comprising a plurality of liquid crystal molecules 14. A plurality of layers 15 are aligned in the same direction and a structure in which the layers 15 are bent occurs. At this time, it is preferable that the major axis of the liquid crystal molecule 14 is inclined for the substrates 11 and 12 at a pretilt angle of, preferably, 5° or more. As for the above aligning state, it is desirable that the orienting process is performed to the substrates 11 and 12 by rubbings 16 and 17 in the same direction.

FIG. 2 is a plan view of the device in which the FLC 13 of the above chevron structure is formed. Reference numeral 21 in FIG. 2 denotes a sealing material to seal the substrates 11 and 12. Although not shown, in the above device, a plurality of a first group of belt-shaped electrodes to apply a voltage are arranged on the substrate 11, and a plurality of second group of belt-shaped electrodes are arranged on the substrate 12 so as to cross the first group of belt-shaped electrodes, thereby forming matrix electrodes. A normal line 22 (on a plane surface) of the layer 15 of the FLC 13 is substantially parallel with the rubbing directions 16 and 17. In the device shown in FIG. 2, the liquid crystal molecules 14 are uniformly tilted to the left (on the plane surface) at an angle of +θ (spontaneous polarization is set to a polarity directing from the upper portion of the paper surface to the lower portion).

According to the experiments by the inventors et al., by applying a voltage (for instance, AC voltage of ±8 volts at 10 Hz) across the upper and lower electrodes of the above matrix electrodes under such a state, the liquid crystal molecules 14 start flowing toward the right side in the layer 15. When such a voltage is continuously applied for a long time (for instance, 20 to 50 hours), as shown in FIG. 3, a region 31 in which the number of liquid crystal molecules 14 has decreased or which has been depleted occurs in the left side portion. On the other hand, a region 32 in which the number of liquid crystal molecules 14 has increased is formed in the right side portion. The inventors consequently have discovered a problem: that an interference color appears over the whole plane surface of the device and the display quality is lost.

In the case where the liquid crystal molecules 14 in FIG. 2(c) are tilted to the right (on the plane surface) at an angle of -θ (spontaneous polarization is set to a polarity directed from the lower portion on the paper surface to the upper portion), it has been also found out that the liquid crystal molecules start flowing toward the left side on the contrary to the above case.

SUMMARY OF THE INVENTION

It is an object of the invention to provide a liquid crystal device or a display apparatus which can solve or suppress the above problems.

According to the invention, there is provided a liquid crystal device having a first substrate on which a first group of belt-shaped electrodes are formed, a second substrate on which a second group of belt-shaped electrodes are formed so as to cross the first group of belt-shaped electrodes, and a chiral smectic liquid crystal arranged between the first and second substrates, wherein a first pretilt angle of the liquid crystal on the first group of belt-shaped electrodes differs from a second pretilt angle of the liquid crystal in the spaces among the belt-shaped electrodes.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross sectional view showing a liquid crystal aligning state used in the invention;

FIG. 2(a) is a plan view of FIG. 1;

FIG. 2(b) is an enlarged plan view of FIG. 2(a);

FIG. 2(c) is an enlarged plan view of FIG. 2(b);

FIG. 3 is a plan view showing a state in the case where a conventional device is used;

FIG. 4A is a plan view showing a device of the invention;

FIG. 4B is a plan view of a substrate 12 used in the device of the invention;

FIG. 5 is a block diagram of a display apparatus of the invention; and

FIGS. 6 and 7 are waveform diagrams showing driving waveforms used in the invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

An embodiment of the invention is shown in FIGS. 4A and 4B. The substrate 11 in FIG. 4A is constructed by: a glass substrate 40a; a first group of belt-shaped electrodes 41a; a film 42a of an inorganic insulating material such as tantalum oxide (Ta₂ O₅) or the like; and a homogeneous orientation film 43a such as a polyimide film which has been rubbing processed. The substrate 12 is constructed by: a glass substrate 40b; a second group of belt-shaped electrodes 41b (which cross the belt-shaped electrodes 41a); a film 42b of an inorganic insulating material such as tantalum oxide (Ta₂ O₅) or the like; an orientation film 43b such as a polyimide film (the same kind as the orientation film 43a) which has been rubbing processed; and second homogeneous orientation films 44 arranged in spaces among the belt-shaped electrodes 41b.

The first group of belt-shaped electrodes 41a and the second group of belt-shaped electrodes 41b are formed by transparent conductive films having thicknesses in a range from 300Å to 3000Å. In addition to Ta₂ O₅, TiO₂, SnO₂, or the like can be used as a film of the inorganic insulating material and such a film is formed so as to have a thickness within a range from 500Å to 5000Å.

As for the substrate 12, by pattern-processing an ITO (indium tin oxide) film having a thickness of 1000Å formed on the glass substrate 40b by a predetermined photo lithography, the belt-shaped transparent electrodes 41b are formed on the glass substrate 40b and, after that, a Ta₂ O₅ film having a thickness of 1000Å is formed by a sputtering method. Further, a polyamic acid film as a precursor of the polyimide film is formed on the Ta₂ O₅ film. After that, by sintering the substrate 12, a polyimide film containing fluorine having a thickness of 300Å and serving as an orientation film 42b is formed. After that, resist films are further formed in the portions corresponding to the belt-shaped transparent electrodes 41b. Subsequently, the substrate 12 is strongly rubbed along the longitudinal direction of the belt-shaped transparent electrodes 41b by an acetate planted blanket in which a wool height is equal to about 2 mm.

The above rubbing process is executed by a method whereby the glass substrate is moved at a speed of 10 mm/sec, two drums each having a diameter of 100 mm and around each of which an acetate planted blanket is adhered are rotated at a rotational speed of 1000 r.p.m. in the progressing direction of the glass, and the drums are come into contact with the glass surface.

At that time, the wools of the rubbing cloth are depressed to the glass substrate by only a length of 0.3 mm. Such a rubbing process which has been executed as mentioned above provides a "strong" rubbing effect. An angle (pretilt angle) between the major axis of the liquid crystal molecule and the interface of the substrate is set to a slightly small value on the substrate surface.

After the strong rubbing process was performed, the resist is peeled off and the substrate is cleaned by a pure water and is dried. After that, the pixel portions are "weakly" rubbed in the same direction as that between the pixels.

The rubbing processing conditions are set such that the glass substrate is moved at a speed of 40 mm/sec and is rubbed by one rubbing drum at a rotational speed of 1000 r.p.m.

The "strong" rubbing portion (belt-shaped transparent electrode 41b) which has been rubbed as mentioned above has a pretilt angle of about 10°, while the "weak" portion (space portion between the belt-shaped transparent electrodes 41b) 44 has a pretilt angle of 18°.

It has been confirmed from the experiments that the molecules in the liquid crystal layer largely move when the pretilt angle is large and that they move small when the pretilt angle is small.

In the embodiment, although the pretilt angles are set to 10° and 18°, it is desirable that the portion (space portion 44) between the pixels has a further small pretilt angle. For instance, according to a method whereby PVA (polyvinyl alcohol) is coated after the surface on the resist was "strongly" rubbed, the pretilt angle of the portion between the pixels is reduced to about 0°.

In the case of coating PVA, since the PVA film is also peeled off at the stage in which the resist is peeled off, it is necessary to set a thickness of PVA film to 1000Å or more.

According to the device shown in FIGS. 4A and 4B FLCs 13 in the intersecting portions among the first group of belt-shaped electrodes 41a and the second group of belt-shaped electrodes 41b are in an alignment state of a chevron structure formed by the liquid crystal of a pretilt angle of 18°. On the other hand, the FLCs in the non-intersecting portions are in an alignment state of the chevron structure formed by the liquid crystal of a pretilt angle of 10°.

According to the invention, the processes performed to the substrate 12 as mentioned above are also applied to the substrate 11. The pretilt angle of the liquid crystal on the belt-shaped transparent electrode 41a can be set to 18°. The pretilt angle of the liquid crystal in the space between the belt-shaped transparent electrodes 41a can be set to 10°.

According to the invention, the pretilt angles of the liquid crystals on the belt-shaped transparent electrodes 41a and/or 41b are preferably set to 15° or more and, more particularly, they are desirable set to angles within a range from 17° to 45°. By setting the pretilt angle of the liquid crystal in the space between the belt-shaped transparent electrodes to an angle within a range from 5° to 15°, the above problems can be effectively suppressed or solved.

FIG. 5 is a block diagram illustrating a structural arrangement of an embodiment of the display apparatus according to the present invention. A display panel 51 (shown in FIG. 4) is composed of scanning electrodes 52, data electrodes 53, and an FLC having the chevron structure shown in FIG. 1 and disposed therebetween. The orientation of the ferroelectric liquid crystal is controlled by an electric field at each intersection of the scanning electrodes and data electrodes formed due to voltages applied across the electrodes.

The display apparatus includes a data electrode driver circuit 54, which in turn comprises an image data shift register 541 for storing image data serially supplied from a data signal line 56, a line memory 542 for storing image data supplied in parallel from the image data shift register 541, a data electrode driver 543 for supplying voltages to the data electrodes 53 according to the image data stored in the line memory 542, and a data side power supply changeover unit 544 for changing over among voltages V_(D), O, and -V_(D) supplied to the data electrodes 53 based on a signal from a changeover control line 511.

The display apparatus further includes a scanning electrode driver circuit 55, which in turn comprises a decoder 551 for designating a scanning electrode among all of the scanning electrodes based on a signal received from a scanning address data line 57, a scanning electrode driver 552 for applying voltages to the scanning electrodes 52 based on a signal from the decoder 551, and a scanning side power supply changeover unit 553 for changing over among voltages V_(S), O, and -V_(S) supplied to the scanning electrodes 52 based on a signal from the changeover control line 511.

The display apparatus further includes a CPU 58, which receives clock pulses from an oscillator 59, controls an image memory 510, and controls the signal transfer over the data signal line 56, scanning address data line 57, and changeover control line 511.

FIG. 6 shows a set of drive voltage signal waveforms used in the present invention. In one scanning selection period, a scanning selection signal having alternating voltages +V_(S) and a voltage 0 is applied to a scanning electrode, wherein the voltages ±V_(S) and the voltage 0 are values defined with reference to the voltage level of a scanning non-selection signal. The data electrodes are supplied with a black or white data signal depending on given data. In the embodiment, the pixels on a scanning electrode supplied with a scanning selection signal are simultaneously erased into a black state in a period T₁ during one scanning selection period, and then in a subsequent period T₂, a pixel supplied with a data signal (B) is set to a black state and a pixel supplied with a data signal (W) is set to a white state.

In the apparatus of the present invention, temperature compensation may be effected by modulating (changing) the length of one scanning selection period (1H) and the magnitude of a drive voltage peak value V_(OP) (capable of writing in black or white) which is V_(OP1) or V_(OP2) giving a maximum value during the period T₂.

FIG. 7 is a waveform diagram showing an example of a sequence of applying a scanning selection signal shown in FIG. 6 to the scanning electrodes. According to the scanning sequence shown in FIG. 7, a scanning selection signal is sequentially applied to the scanning electrodes S₁, S₂, . . . , S_(F8+8)(s-1) every 8th electrode (7 electrodes apart) in one vertical scanning (field scanning) and one picture is formed through 8 times of field scanning to complete one frame scanning. In this instance, in each field scanning, the scanning selection signal is also applied to the scanning electrodes S_(A) and S_(B) in the non-display region. In FIG. 7, the symbols F₁, F₂, . . . , F₈ each represents an ordinal number of field scanning in one frame scanning and the symbol s represents an ordinal number of scanning in one field scanning.

A series of experiments were conducted wherein the above-mentioned display operation was repeated by using a ferroelectric liquid crystal panel with the dimensions and drive conditions as shown below and the driving signal waveforms shown in FIGS. 6 and 7 while applying the scanning selection signal to the scanning electrodes 52 electrodes apart (in every 8th electrode). 

What is claimed is:
 1. A method of fabricating a chiral smectic liquid crystal display device, said device comprising a first substrate provided with a first plurality of electrodes and a second substrate provided with a second plurality of electrodes facing and intersecting said first plurality of electrodes to define a matrix arrangement of pixels and having a chiral smectic liquid crystal interposed between said first and second substrates, said method comprising the steps of:selecting said pair of substrates; patterning said first plural electrodes on said first substrate and patterning said second plural electrodes on said second substrate; forming on said first and second substrates an organic insulating film followed by a homogeneous orientation film; forming a resist on said orientation film on at least one of said fist or second substrates in the areas between said plurality of electrodes and providing a rubbing effect to said substrate along the longitudinal direction of said electrodes; removing said resist and imparting another rubbing effect to said substrate along the longitudinal direction of said electrodes; assembling said first and second substrates to provide a display cell; and imparting into said display cell a chiral smectic liquid crystal in a layer structure. 